Crude oils, heavy fuel oils, lubricating oils, tars, asphalts, and bituminous fluxes. Centrifugation (BS&W) 0.01% to 1.5%
⚠️ (e.g., docplayer, academia.edu). They often host outdated or pirated copies, and ASTM actively enforces copyright.
A graduated receiver (typically 5 mL, 10 mL, or 25 mL capacity) calibrated to measure small increments of water.
Allow the trap to cool to room temperature. If any water droplets adhere to the glass walls, nudge them down into the graduated section using a glass stirring rod or Teflon scraper. Read the volume of water directly from the graduations. 5. Calculations and Reporting Astm D95 Pdf
: The petroleum sample is mixed with the solvent and heated. Because water and the solvent form an azeotrope, they boil and vaporize together at a lower temperature than their individual boiling points. Condensation
[ Petroleum Sample + Water-Immiscible Solvent ] │ ▼ (Applied Heating) [ Vaporization of Co-Distilled Solvent & Water ] │ ▼ (Reflux Condenser Assembly) [ Continuous Separation inside a Graduated Trap ] │ ▼ [ Water Settles at Bottom / Solvent Recycles Back ]
ASTM D95 does not exist in isolation; several other ASTM standards are closely related. Understanding these standards can provide a more complete picture of the testing landscape. Crude oils, heavy fuel oils, lubricating oils, tars,
: Refineries use the test to ensure that crude oil feedstocks meet quality specifications, helping to prevent operational issues and ensure the production of high-quality products.
Note: is technically identical in principle to D95 but applies only to crude oil. For most petroleum products, D95 is the broader standard.
When you search for , you will find many unofficial summaries, slides, or pirated copies. Be aware: Using an unauthorized PDF can lead to laboratory non-compliance, failed audits, or incorrect testing procedures. A graduated receiver (typically 5 mL, 10 mL,
ASTM D95 is a standardized distillation method used to measure water content (0–25% by volume) in petroleum products and bituminous materials, crucial for ensuring quality and accurate custody transfer. Utilizing the Dean-Stark principle, this method employs solvent reflux to separate water, preventing operational hazards like corrosion and refining inefficiencies. For technical specifications and the full standard, refer to Shanghai Minglan Chemical Co.,Ltd.
Drops sticking to the condenser walls or trap sides cause falsely low readings. Use a rinse solvent or physical rod to drop them into the graduated layer.
It is less accurate for samples containing trace amounts of water (below 0.05%).
The condensed liquids drop into a graduated glass trap. Because water is denser than the solvent and completely immiscible, it separates and settles at the bottom of the trap, while the excess solvent overflows back into the distillation flask.
Refining crude oil with high water content causes rapid pressure spikes in distillation columns, putting refinery infrastructure at risk of explosions or emergency shutdowns. ASTM D95 vs. Karl Fischer Titration (ASTM E203 / D6304)